촉매화학증착법으로 제조한 나노 탄소섬유/튜브

김명수; Myung Soo Kim

Journal of the Korean Industrial and Engineering Chemistry, Vol.11, No.5, 479-488, August, 2000

Export Citation

촉매화학증착법으로 제조한 나노 탄소섬유/튜브

Carbon Nanofiber/Nanotube by Catalytic Chemical Vapor Deposition

김명수 ^†

명지대학교 세라믹화학공학부, 용인 449-728

Myung Soo Kim^†

Division of Ceramic and Chemical Engineering, Myongji University, Yongin 449-728, Korea

E-mail:

초록

촉매화학증착법은 나노탄소섬유와 튜브를 포함하여 다양한 물질을 제조하는 잘 확립된 방법으로, 저온성장법으로 대량생산에 적합하다는 장점을 가지고 있다. 공정변수를 적절히 선택하면, 특정한 성장모드와 결정화도를 갖는 기상성장탄소섬유(나노탄소섬유와 튜브)를 제조하는 것이 가능하다. 기상성장탄소섬유의 이용기술 몇 가지를 소개하였다.

Catalytic chemical vapor deposition (CCVD) is a well established method for synthesis of a wide range of materials including nanofibers and nanotubes. Its primary advantage is that it is low temperature technique and suitable for large scale production. By careful manipulation of various process parameters, it is possible to produce vapor-grown carbon fibers (nanofibers and nanotubes) in assorted conformation as well as to control their crystalline order. Some applications of vapor-grown carbon fibers are introduced.

Keywords:CCVD;VGCF;Carbon nanofiber;Carbon nanotube;Catalyst particle

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Oberin A, Endo M, Koyama T, J. Cryst. Growth, 32, 335 (1976)
Rodriguez NM, J. Mater. Res., 8(12), 3233 (1993)
Kim MS, Baker RTK, "Mitigation of Coke Formation on Alloy Surface," The Pennsylvania State University Report, U.S.A. (1993)
Kim MS, "Influence of selected Metal Catalysts on Carbon Felament formation," Ph.D. Thesis, Auburn University, Auburn, U.S.A. (1991)
Rodriguez NM, Chambers A, Baker RT, Langmuir, 11(10), 3862 (1995)
Baker RTK, Barber MA, Feates PS, Harris FS, Waite RJ, J. Catal., 26, 51 (1972)
Rostrup-Nielsen J, Trimm DL, J. Catal., 48, 155 (1977)
Alstrup I, J. Catal., 109, 241 (1988)
Bianchini EC, Lund CRF, J. Catal., 117, 455 (1989)
Endo M, Saito R, Dresselhaus M, Dresselhaus G, "Carbon Nanotubes," ed. T.W., Ebbesen, 35, CRC Press, New York (1997)
Andrews R, Jacques D, Rao AM, Derbyshire F, Qian D, Fan X, Dickey EC, Chen J, Chem. Phys. Lett., 303, 476 (1999)
Sinfelt JH, Carter JL, Yate JC, J. Catal., 24, 283 (1972)
Best RJ, Russell WW, J. Am. Chem. Soc., 76, 838 (1954)
Koyama T, Endo MT, Japanese Patent, 1982-58, 966 (1982)
Tibbetts GG, Bernardo CA, Gorkiewicz DW, Alig RL, Carbon, 32, 569 (1994)
Kim MS, Im YS, Korean Patent, 0252792 (2000)
Motojima S, Iwagana H, Kagiya S, Momiyama M, Appl. Phys. Lett., 62(19), 2322 (1993)
Motojima S, Hasegawa I, Kagiya S, Andoh K, Iwagana H, Carbon, 33, 1167 (1995)
Rodriguez NM, Kim MS, Baker RTK, Proceedings of International Carbon Conference, Granada, Spain, July, 524 (1994)
Lu W, Chung DDL, Carbon, 35, 427 (1997)
Maire J, Mering J, "Chemistry and Physics of Carbon," ed. P.L. Walker, 6, 125 (1970)
Kim MS, Rodriguez NM, Baker RTK, J. Catal., 131, 60 (1991)
Kim MS, Kim DY, HWAHAK KONGHAK, 36(1), 34 (1998)
정의남, 이학민, 제 1회 탄소재료의 개발과 응용에 관한 Work-shop, 충남대, 95 (1995)
Shui X, Frysz CA, Chung DDL, Carbon, 35, 1439 (1997)
Frysz CA, Chung DDL, Carbon, 35, 1111 (1997)
Geus JW, Workshop Sponsered by the American Carbon Society, "Carbon as a Catalyst Support," Atlanta, May, 1992 (1992)
Vissers JPR, Scheffers RG, De Beer VHJ, Moolijn JA, Prins R, J. Catal., 105, 277 (1987)
You SG, Chem. Ind. Technol., 12(1), 6 (1994)
Rodriguez NM, Kim MS, Baker RT, J. Phys. Chem., 98(50), 13108 (1994)
Chambers A, Nemes T, Rodriguez NM, Baker RTK, J. Phys. Chem. B, 102(12), 2251 (1998)
Park C, Baker RTK, J. Phys. Chem. B, 102(26), 5168 (1998)
Kim MS, Rodriguez NM, Baker RTK, Mater. Res. Soc., 368, 99 (1995)
Rodriguez MN, Baker RTK, U.S. Patent, 5,653,951 (1995)
Alcaniz-Monge J, Casa-Lillio MA, Cazola-Amoros D, Linares-Solano A, Carbon, 35, 291 (1997)
Motojima S, Iwagana H, Tanso, 174, 215 (1996)
Han WQ, Fan SS, Li QQ, Hu YD, Science, 277(5330), 1287 (1997)
Dai HJ, Wong EW, Lu YZ, Fan SS, Lieber CM, Nature, 375(6534), 769 (1995)
Zhu J, Fan S, J. Mater. Res., 14(4), 1175 (1999)
신현익, 송현종, 김명수, 임연수, 이재춘, 한국세라믹학회지, 37(4), 376 (2000)
김재호, 화학세계, 36(10) (1996)

[Referenced By]

[Related Articles]

[1] Iijima S, Nature, 354, 56 (1991)

[2] Bucky U.S.A., http://bucky5.wustl.edu/Science/Nanofiber_Growth.html

[3] Tibbettes GG, Appl. Phys. Lett., 42, 66 (1983)

[4] Hyperion Catalysis International, http://www.fibrils.com/conplas1.htm

[5] Hyperion Catalysis International, http://www.fibrils.com/ultracap.htm

[6] Hyperion Catalysis International, http://www.fibrils.com/first.htm

[7] Baker RTK, http://itri.loyola.edu/nano/us_r_n_d/09_03.htm

[8] Oberin A, Endo M, Koyama T, J. Cryst. Growth, 32, 335 (1976)

[9] Rodriguez NM, J. Mater. Res., 8(12), 3233 (1993)

[10] Kim MS, Baker RTK, "Mitigation of Coke Formation on Alloy Surface," The Pennsylvania State University Report, U.S.A. (1993)

[11] Kim MS, "Influence of selected Metal Catalysts on Carbon Felament formation," Ph.D. Thesis, Auburn University, Auburn, U.S.A. (1991)

[12] Rodriguez NM, Chambers A, Baker RT, Langmuir, 11(10), 3862 (1995)

[13] Baker RTK, Barber MA, Feates PS, Harris FS, Waite RJ, J. Catal., 26, 51 (1972)

[14] Rostrup-Nielsen J, Trimm DL, J. Catal., 48, 155 (1977)

[15] Alstrup I, J. Catal., 109, 241 (1988)

[16] Bianchini EC, Lund CRF, J. Catal., 117, 455 (1989)

[17] Endo M, Saito R, Dresselhaus M, Dresselhaus G, "Carbon Nanotubes," ed. T.W., Ebbesen, 35, CRC Press, New York (1997)

[18] Andrews R, Jacques D, Rao AM, Derbyshire F, Qian D, Fan X, Dickey EC, Chen J, Chem. Phys. Lett., 303, 476 (1999)

[19] Sinfelt JH, Carter JL, Yate JC, J. Catal., 24, 283 (1972)

[20] Best RJ, Russell WW, J. Am. Chem. Soc., 76, 838 (1954)

[21] Koyama T, Endo MT, Japanese Patent, 1982-58, 966 (1982)

[22] Tibbetts GG, Bernardo CA, Gorkiewicz DW, Alig RL, Carbon, 32, 569 (1994)

[23] Kim MS, Im YS, Korean Patent, 0252792 (2000)

[24] Motojima S, Iwagana H, Kagiya S, Momiyama M, Appl. Phys. Lett., 62(19), 2322 (1993)

[25] Motojima S, Hasegawa I, Kagiya S, Andoh K, Iwagana H, Carbon, 33, 1167 (1995)

[26] Rodriguez NM, Kim MS, Baker RTK, Proceedings of International Carbon Conference, Granada, Spain, July, 524 (1994)

[27] Lu W, Chung DDL, Carbon, 35, 427 (1997)

[28] Maire J, Mering J, "Chemistry and Physics of Carbon," ed. P.L. Walker, 6, 125 (1970)

[29] Kim MS, Rodriguez NM, Baker RTK, J. Catal., 131, 60 (1991)

[30] Kim MS, Kim DY, HWAHAK KONGHAK, 36(1), 34 (1998)

[31] 정의남, 이학민, 제 1회 탄소재료의 개발과 응용에 관한 Work-shop, 충남대, 95 (1995)

[32] Shui X, Frysz CA, Chung DDL, Carbon, 35, 1439 (1997)

[33] Frysz CA, Chung DDL, Carbon, 35, 1111 (1997)

[34] Geus JW, Workshop Sponsered by the American Carbon Society, "Carbon as a Catalyst Support," Atlanta, May, 1992 (1992)

[35] Vissers JPR, Scheffers RG, De Beer VHJ, Moolijn JA, Prins R, J. Catal., 105, 277 (1987)

[36] You SG, Chem. Ind. Technol., 12(1), 6 (1994)

[37] Rodriguez NM, Kim MS, Baker RT, J. Phys. Chem., 98(50), 13108 (1994)

[38] Chambers A, Nemes T, Rodriguez NM, Baker RTK, J. Phys. Chem. B, 102(12), 2251 (1998)

[39] Park C, Baker RTK, J. Phys. Chem. B, 102(26), 5168 (1998)

[40] Kim MS, Rodriguez NM, Baker RTK, Mater. Res. Soc., 368, 99 (1995)

[41] Rodriguez MN, Baker RTK, U.S. Patent, 5,653,951 (1995)

[42] Alcaniz-Monge J, Casa-Lillio MA, Cazola-Amoros D, Linares-Solano A, Carbon, 35, 291 (1997)

[43] Motojima S, Iwagana H, Tanso, 174, 215 (1996)

[44] Han WQ, Fan SS, Li QQ, Hu YD, Science, 277(5330), 1287 (1997)

[45] Dai HJ, Wong EW, Lu YZ, Fan SS, Lieber CM, Nature, 375(6534), 769 (1995)

[46] Zhu J, Fan S, J. Mater. Res., 14(4), 1175 (1999)

[47] 신현익, 송현종, 김명수, 임연수, 이재춘, 한국세라믹학회지, 37(4), 376 (2000)

[48] 김재호, 화학세계, 36(10) (1996)