Various Bunsen flame information of premixed syngas/air mixtures was systematically collected. A CCD camera was used to capture the flame images. The OH-PLIF technique was applied to obtain the flame OH distribution and overall flame radiation spectra were measured with a spectrograph. Experiments were conducted on a temperature uncontrolled burner and syngas over a wide range of H-2/CO ratios (from 0.25 to 4) and equivalence ratios (from 0.5 to 1.2). Results show that increasing hydrogen fraction (X-H2) extends the blow-off limit significantly. The measured laminar flame speed using cone-angle method based on CCD flame imaging and OH-PLIF images increases remarkably with the increase of X-H2, and these measurements agrees well with kinetic modeling predictions through Li's mechanism when the temperature for computation is corrected. Kinetic study shows that as X-H2, increases, the production of H and OH radicals is accelerated. Additionally, the main H radical production reaction (or OH radical consumption reactions) changes from R29 (CO + OH = CO2 + H) to R3 (H-2 + OH = H2O + H) as X-H2 increases. Sensitivity analysis was conducted to access the dominant reactions when X-H2 increases. The difference on flame color for different X-H2 mixtures is due to their difference in radiation spectrum of the intermediate radicals produced in combustion. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.