화학공학소재연구정보센터
Journal of Chemical Physics, Vol.108, No.16, 6857-6860, 1998
Molecular size and luminescence decay influenced by energy transfer by the exchange mechanism
The decay law has been investigated theoretically when electronic excitation energy transfer is efficient. The concept of a nonvanishing closest donor-acceptor distance has been introduced into the theory of Inokuti and Hirayama for energy transfer by exchange interaction. A previous report of Hara and Condo on the same subject based on Inokuti-Hirayama's theory has been examined and some mistakes have been found in the theory and experiment. Careful treatment of equations yields a decay law different from that of Hara and Condo. The inclusion of the closest donor-acceptor distance modifies the decay form significantly.