This paper investigates a potential cathode material (La0.2Sr0.8)(0.9)Ti0.9Cu0.1O3-delta (LSTCO) with A-site deficiency and B-site excess which was designed as a parent material for anchoring exsolved copper nanocatalyst on the surface of La0.2Sr0 8TiO3+delta (LSTO) through a high-temperature reduction. Physical characterization of the samples by combined use of X-ray diffraction, scanning electron microscope, energy-dispersive spectroscopy, thermogravimetric analyzer and X-ray photoelectron spectroscopy indicated that the exsolution and dissolution of the Cu nanoparticles in the cathode was completely reversible in the redox cycles. Electrical properties of LSTO and LSTCO were systematically investigated which correlated closely with electrochemical performance of the composite electrodes in symmetrical cells and electrolysis cells. Polarization resistance (R-p) of the symmetrical cells was improved from 3 Omega cm(2) of the LSTO to 1.5 Omega cm(2) of the LSTCO in hydrogen atmosphere at 800 degrees C. Current efficiencies of the solid oxide electrolyzer with Cu-anchored LSTO cathode were found to be enhanced by approximately 20% compared to the bare cathode with or without reducing gas flowing over them under the applied voltage of 2.0 Vat 800 degrees C, respectively. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.