The explosion process of multi-component gas mixture is extremely complex and may cause serious disaster effects. The safety issue concerning explosion of multi-component gas mixture is urgent to be investigated on account of its wide range of applications. In current work, series of experiments were performed in a 20 L spherical explosion vessel at initial conditions of 1 atm and 293K, involving methane-hydrogen/air mixtures. The proportion of hydrogen in fuels varied from 0% to 100%. It was observed that peak temperature is always behind the peak pressure in arrival time whatever the fuel equivalence is. Experimental values of peak overpressure are lower than adiabatic ones due to heat loss. It was also founded that the hydrogen addition can raise explosion pressure and temperature in experiment but slightly decrease that in adiabatic condition, and both the increase in experiment and the decrease in adiabatic show a linear correlation versus the proportion of hydrogen. Hence the deviation between the experimental results and the adiabatic results decreases as the hydrogen proportion rises. Moreover, the positive effect of hydrogen addition on (dp/dt)(max) is very slight at low hydrogen proportion, while the effect becomes much more pronounced at higher hydrogen contents, showing an exponential growth. For each fuel composition throughout all experiments, the peak overpressure, peak temperature and (dp/dt)(max) concerning fuel equivalence ratios of 0.6, 1 and 1.5 follow a same rule: Phi = 1 is the highest, followed by Phi = 1.5 and Phi = 0.6. Finally, the MIEs of gaseous methane-hydrogen/air mixtures at a fuel equivalence ratio of 1.5 were measured as a function of hydrogen proportion. It shows a sharp decrease as the fraction of hydrogen in fuel rises, from 118 mJ for methane-air to 0.12 mJ for hydrogen-air. It is also observed that the MIE of multi-component gas mixtures can be approximately figured as the linear weighted sum of the MIE of each component; the weighting factor is respectively the volume fraction of each component. This can be considered as a universal method to obtain the MIE for a specific multi-component gas. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.