To improve our knowledge about the factors controlling the partitioning of ammonia/ammonium and nitric acid/nitrate among the gas phase, fine particles, and coarse particles, a year-round observation of these species in the gaseous and particulate phases was conducted at an inland rural site in Japan. The partitioning of ammonia/ammonium between the gaseous and particulate phases is strongly controlled by the amount of acidic species that can potentially react with ammonia gas. An excess amount of the acidic species over the sum of ammonia/ammonium facilitates the shift of gaseous ammonia to particulate ammonium. Although the ambient temperature affects the partitioning of nitric acid/nitrate between the gas phase and fine particles, the amount of coarse sea-salt particles dominantly control the partitioning between the gaseous and particulate phases; a large amount of coarse sea-salt particles facilitates the partition of nitrate into the coarse mode range, whereas it prevents the partition of nitric acid into the gas phase. Sea-salt particles would have a critical role for the partition of nitric acid/nitrate among the gas phase, fine particles, and coarse particles, even in the inland area with lower amounts of sea-salt particles. An excessive amount of ammonia/ammonium for complete neutralization of the particulate non-sea-salt sulfate is also important for the partitioning and its lack is unfavorable for the generation of nitrate in the fine particles even under lower temperature conditions. (C) 2012 Elsevier Ltd. All rights reserved.