화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.72, 37-43, 2014
To the issue of temperature-dependent behavior of standard molar volumes of components in the binary system (water plus tetrahydrofuran) at ambient pressure
This report presents a comparative analysis of temperature-dependent data on density of both dilute aqueous solutions of tetrahydrofuran (THF) and dilute solutions of water in THF, as well as standard molar volumes of water or THF as a solute. For this purpose, new results on studying the volume-related properties of THF in a water-rich region at temperatures from (278.15 to 318.15) K, with a step of 5 K, and at the ambient pressure have been derived densimetrically. In discussion, some comments on previously published investigations, being related to temperature-dependent changes in the solution density and standard molar volumes of components of the system (water + THF), have been made. (c) 2013 Elsevier Ltd. All rights reserved.