The synthesis and characterization of two europium alkoxides, Eu(OCH3)(2) and Eu(OC2H5)(2), were described. For the first time the enthalpies of formation of divalent lanthanide alkoxides were determined by using reaction-solution calorimetry. The values obtained are Delta H-f(0) [Eu(OCH3)(2), cr] = -850.5 +/- 5.0 kJ/mol and Delta H-f(0) [Eu(OC2H5)(2), cr] = -902.5 +/- 5.5 kJ/mol, respectively. Since these compounds have a large use as catalysts or catalysts precursors, the first step of the reaction of them with CO2 was addressed, which permits to have an idea of the kind of bond involved in those compounds. Moreover, insertion of CO2 in the europium oxygen bond and formation of metal carboxylate complexes, is in both cases presumably bidentate. (C) 2014 Elsevier Ltd. All rights reserved.