New Progress in Conducting Polyaniline

Wang F; Jing X

Korea Polymer Journal, Vol.4, No.2, 89-93, October, 1996

New synthesis system was established to prepare polyaniline (PAn) with controlled molecular weight. The synthesized PAn was completely soluble in many organic solvents such as dimethylsulfoxide (DMSO), dimethylformamide and N-methylpyrrolidone (NMP). The molecular aggregation due to the interaction between PAn and NMP molecules was found in dilute PAn/NMP solution. The gelatin of concentrated PAn/NMP solution was a physical crosslinking between PAn molecules with the help of NMP through hydrogen bonding. A gelatin mechanism was proposed.

[References]

MacDiarmid AG, Epstein AJ, J. Chem. Soc., 88, 317 (1989)
MacDiarmid AG, Conjugated Polymer and Related Materials, Teh Interconnection of Chemical and Electronic Structure, W.R. Salaneck, I. Lundstro and B. Ranby, Eds., Oxford University Press, pp. 73-98 (1993)
Epstein AJ, MacDiarmid AG, Synth. Met., 9, 179 (1995)
Sethi RS, Goosey MT, Special Polymers for Electronics and Optoelectronics, J.A. Chilton and M.T. Goosey, Eds., Chapman & Hall, pp. 1-36 (1995)
Wessling B, Adv. Mater., 6, 226 (1994)
Trivedi DC, Dhawan SK, Synth. Met., 267 (1993)
Venugopal G, Chem. Mater., 7, 271 (1995)
Geneis EM, Noel P, Synth. Met., 46, 285 (1992)
Cao Y, Andreatta A, Heeger AJ, Smith P, Polymer, 30, 2305 (1989)
Geng YH, Li J, Wang XH, Jing WB, Wang FS, Chinese Patent, Appl. No. 95 108490.9 (1995)
MacDiarmid AG, Epstein AJ, Science and Applications of Conducting Polymers, W.R. Salaneck, D.T. Clark, and E.J. Samuelson, Eds. Adam Hilger, Bristol, UK, pp. 117-127 (1991)
Moon DK, Osakada K, Maruyama T, Yamamoto T, Makromol. Chem., 193, 1723 (1992)
Misra GS, Baipai UDN, Prog. Polym. Sci., 8, 61 (1982)
Wang FS, Jing XB, Wang XH, Dong AJ, Synth. Met., 69, 93 (1995)
Fuoss RM, Cathers GI, J. Polym. Sci., 4, 97 (1949)
Dong AJ, Jing XB, Wang W, Feng ZL, Chinese J. Appl. Chem., 11, 62 (1994)

[1] MacDiarmid AG, Epstein AJ, J. Chem. Soc., 88, 317 (1989)

[2] MacDiarmid AG, Conjugated Polymer and Related Materials, Teh Interconnection of Chemical and Electronic Structure, W.R. Salaneck, I. Lundstro and B. Ranby, Eds., Oxford University Press, pp. 73-98 (1993)

[3] Epstein AJ, MacDiarmid AG, Synth. Met., 9, 179 (1995)

[4] Sethi RS, Goosey MT, Special Polymers for Electronics and Optoelectronics, J.A. Chilton and M.T. Goosey, Eds., Chapman & Hall, pp. 1-36 (1995)

[5] Wessling B, Adv. Mater., 6, 226 (1994)

[6] Trivedi DC, Dhawan SK, Synth. Met., 267 (1993)

[7] Venugopal G, Chem. Mater., 7, 271 (1995)

[8] Geneis EM, Noel P, Synth. Met., 46, 285 (1992)

[9] Cao Y, Andreatta A, Heeger AJ, Smith P, Polymer, 30, 2305 (1989)

[10] Geng YH, Li J, Wang XH, Jing WB, Wang FS, Chinese Patent, Appl. No. 95 108490.9 (1995)

[11] MacDiarmid AG, Epstein AJ, Science and Applications of Conducting Polymers, W.R. Salaneck, D.T. Clark, and E.J. Samuelson, Eds. Adam Hilger, Bristol, UK, pp. 117-127 (1991)

[12] Moon DK, Osakada K, Maruyama T, Yamamoto T, Makromol. Chem., 193, 1723 (1992)

[13] Misra GS, Baipai UDN, Prog. Polym. Sci., 8, 61 (1982)

[14] Wang FS, Jing XB, Wang XH, Dong AJ, Synth. Met., 69, 93 (1995)

[15] Fuoss RM, Cathers GI, J. Polym. Sci., 4, 97 (1949)

[16] Dong AJ, Jing XB, Wang W, Feng ZL, Chinese J. Appl. Chem., 11, 62 (1994)