Journal of Colloid and Interface Science, Vol.423, 101-107, 2014
Spray-coating of superhydrophobic aluminum alloys with enhanced mechanical robustness
A superhydrophobic aluminum alloy was prepared by one-step spray coating of an alcohol solution consisting of hydrophobic silica nanoparticles (15-40 nm) and methyl silicate precursor on etched aluminum alloy with pitted morphology. The as-sprayed metal surface showed a water contact angle of 155 and a roll-off angle of 4. The coating was subjected to repeated mechanical tests, including high-pressure water jetting, sand particles impacting, and sandpaper shear abrasion. It remained superhydrophobic with a roll-off angle <10 degrees up to three cycles of water jetting (25 kPa for 10 min) and sand particle impinging. After five cycles, the roll-off angle increased, but no more than 19 degrees while the water contact angle remained greater than 150 degrees. The superhydrophobic state was also maintained after three cycles of sandpaper abrasion. It was found that the micro-protrusion structures on the etched aluminum alloy played an important role to enhance the coating mechanical robustness, where the nanoparticles could grab on the rough surface, specifically in the groove structures, in comparison with the smooth glass substrates spray coated with the same materials. Further, we showed that the superhydrophobicity could be restored by spray a new cycle of the nanocomposite solution on the damaged surface. (C) 2014 Elsevier Inc. All rights reserved.
Keywords:Superhydrophobic surfaces;Silica nanoparticles;Polymethylsiloxane;Spray coating;Mechanical robustness