화학공학소재연구정보센터
Journal of Crystal Growth, Vol.363, 282-286, 2013
Ultra-violet GaN/Al0.5Ga0.5N quantum dot based light emitting diodes
Taking advantage of the strain-induced 2-dimensional (2D)-3D "Stransky-Krastanov type" growth mode of GaN on AlxGa1-xN, we re port on the fabrication of ultraviolet (UV) light emitting diodes (LEDs) using GaN quantum dots (QDs) as emitters. The structures have been grown by molecular beam epitaxy on sapphire (0001) substrates. GaN QDs, with density similar to 8 x 1010 cm(-2), are formed on Al0.5Ga0.5N layers. The electroluminescence (EL) spectrum is dominated by a blue-violet emission (400-430 nm) at very low injection currents (<= 2 A/cm(2)). At currents above 10 A/cm(2), a UV emission (<390 nm) is observed. An additional peak, at wavelength similar to 314 nm, originates from the EL emission from the GaN wetting layer. For increasing current, we observe a large shift (similar to 300 meV) towards higher energies and a reduction by one third of the full width at half maximum of the EL peak. Furthermore, the appearance of an additional peak on the EL high energy side is observed. These properties are governed by the quantum confined Stark effect and band-filling in the QDs. AlxGa1-xN-based QD-LED performances (optical power, external quantum efficiency) are presented and discussed in correlation to the specific 3D localization of excitons in the QDs. (C) 2012 Elsevier B.V. All rights reserved.