화학공학소재연구정보센터
Journal of Crystal Growth, Vol.371, 94-101, 2013
Basal plane dislocation conversion near the epilayer/substrate interface in epitaxial growth of 4 degrees off-axis 4H-SiC
The conversion of basal plane dislocations (BPDs) is investigated in the epitaxial growth of 4 degrees off-axis SiC by three approaches: (1) regular growth on untreated substrates, (2) growth on pre-etched substrates and (3) growth-etch-regrowth approach. In the regular growth, similar to 99.0% of the substrate BPDs are converted to threading edge dislocations (TEDs) in the vicinity of the epilayer/substrate interface and the rest similar to 1.0% BPDs are converted throughout the similar to 20 mu m thick epilayer. A modified KOH-NaOH-MgO eutectic mixture is developed to mildly etch the substrate in approach (2) or a grown buffer-layer in approach (3) to enhance BPD conversion rate. In the subsequent epitaxial growth, the BPD conversion rate near the interface is enhanced up to 99.9% in approach (2) and to 100% in approach (3). Using the modified KOH-NaOH-MgO eutectic mixture, very mild etching of the surfaces (substrate or buffer-layer) for a short duration (2-3 min) will generate very small etch pits, and will not degrade the morphology of the etched surfaces and also that of the subsequently grown epilayer surfaces, but very high (similar to 100%) BPD conversion rate is still preserved. Post-polishing process is no longer needed for future device fabrication. It is proposed that the opening of a sector plane in the BPD etch pit, which enables lateral epitaxial growth to pinch off the step-flow growth inside the etch pit, is responsible for the high BPD conversion rate near the interface. The degree of anisotropic etching in the < 11-20 > directions versus the < 1-100 > directions determines the sector open angle of the BPD etch pits. The degree of anisotropic etching is studied for different KOH formulations-pure KOH, regular KOH-NaOH eutectic and the modified KOH-NaOH-MgO eutectic mixture. (C) 2013 Elsevier B.V. All rights reserved.