A comprehensive microstructural evolution of Mg-1.5, 4.0 and 5.5 wt% Zn alloys with respect to the solidification parameters such as thermal gradient (C), solidification velocity (V), cooling rate (CV) and solute (Zn) content were investigated in the present study. Solidification techniques such as directional solidification and wedge casting were employed in order to obtain cooling rates between 0.05 and 250 K/s. Microstructural features such as secondary dendrite arm spacing (SDAS), primary dendrite arm spacing (PDAS), microsegregration along the secondary dendrites and secondary phase fractions were experimentally determined. A solidification model that incorporates solute back diffusion, secondary arm coarsening, dendrite tip undercooling and dynamically linked with accurate thermodynamic databases is used to explain the experimental results. (C) 2014 Elsevier B.V. All rights reserved.