Single crystal growth of the inlermelallic compounds GaPd2, GaPd, and Ga(7)Pcl(3) is described for the first Lime. These phases have recently been explored as highly selective heterogeneous catalysts in the semi hydrogenation of acetylene. Well oriented single crystalline surfaces are needed to perform fundamental studies on catalytic processes. The three Ga-Pd phases were grown using the Czochralski method from Ga-rich solutions. Thermodynamic properties of the Ga-Pd system determine very different growth temperatures reaching from less than 460 degrees C for Ga7Pd3 to about 1200 degrees C for GaPd2. Avoiding mother liquid inclusion formation proved to be the key problem that could be solved by pulling rates sometimes as low as 25 Limiti and forced convection by high crystal rotation rates. In the last grown part of GaPd2 crystals decomposition into GaPd2/Ga3Pd5 lamellas occurred which can be explained either by spinodal decomposition or by nucleation caused by the GaPd2 stability region that becomes narrower with decreasing temperatures. (C) 2013 Elsevier B.V. All rights reserved