Journal of Chemical Physics, Vol.110, No.2, 1230-1234, 1999
Highly charged colloidal suspensions in planar slits
A simple density functional approximation, which is based both on the density functional Taylor series expansion of the one-particle direct correlation function (DCF) and on the exact contact value theorem for a structureless hard wall with infinity wall distance, has been developed to study the structural properties of a highly charged colloidal suspension and compared with the computer simulation. Two kinds of two-particle DCFs, which are the rescaled mean spherical approximation (RMSA) and the Rogers-Young (RY) closure relation, have been used to calculate the local concentration profiles of a highly charged colloidal suspension confined in charged silt walls as input. The calculated results show that for a structureless hard wall the present approximation is better than the hypernetted chain (HNC) functional approximation and describes well the structural properties; of a confined colloidal suspension compared with the computer simulation. However, the agreement between the computer simulation and the theory for the density profiles deteriorates with increasing the wall-particle interaction.
Keywords:DENSITY-FUNCTIONAL APPROACH;CONCENTRATION PROFILE;INTEGRAL-EQUATION;FLUIDS;DISPERSION;CONSISTENT;PARTICLES;INTERFACE;SYSTEM