This paper aims at presenting the evolution of process safety in Spain from various points of view. In first place, a study of the accidents occurred in this country in the process industry and in the transportation of chemical substances is presented. After this, the starting point of the process safety research in Spain and its evolution during the years are explained. The importance of this topic has also been reflected in the chemical engineering studies in some Spanish universities. Therefore, the current status of the studies on process safety in Spain is analyzed in this paper. A section has also been devoted to the process safety in the Spanish industry. An analysis of the related legislation and its implementation in the Spanish process industry is also presented in this paper. Finally, the professional career of Prof. Joaquim Casal, the pioneer in Spain in process safety and risk assessment, is summarized. (C) 2013 Elsevier Ltd. All rights reserved.