The two-dimensional potential energy surfaces for the Ar-CO complex have been developed using single and double excitation coupled-cluster theory with noniterative treatment of triple excitations [CCSD(T)]. The most accurate results have been obtained with the augmented correlation-consistent polarized triple zeta basis set (aug-cc-pVTZ) with an additional (3s3p2d2f1g) set of bond functions. The minimum of -104.68 cm(-1) has been found at (R,Theta)=(3.714 Angstrom, 92.88 degrees), where R and Theta denote the Jacobi coordinates with Theta = 0 degrees corresponding to the linear Ar-OC geometry and Theta = 180 degrees to the linear Ar-CO geometry. Dynamical calculations have been performed to determine the frequencies of various rotational and rovibrational transitions. The overall agreement with experiment is good. For example, the calculated frequencies of the intermolecular bending and stretching vibrations, 12.015 and 18.520 cm(-1), respectively, agree very well with the experimental values (12.014 and 18.110 cm(-1)). (C) 2000 American Institute of Physics. [S0021-9606(00)30310-5].