In this study we fabricate and characterize the properties of photopolymerizable proton exchange membranes, formed from composite blends of poly(ethylene glycol) diacrylate (PEGDA) and sulfonated poly(ethylene glycol) phenyl ether acrylate (sPEGPEA). PEGDA-sPEGPEA blends were produced through free radical photopolymerization and were shown to be easily processed into thin membranes using techniques which are compatible with the fabrication of microfluidic fuel cell devices. Membrane materials were characterized through electrochemical impedance spectroscopy (EIS), Fourier transform infra-red spectroscopy (FTIR), dynamic mechanical analysis (DMA), as well as a host of techniques to measure ion exchange capacity, degree of water absorption, and surface morphology. We show that PEGDA-sPEGPEA membranes possess favourable proton exchange membrane characteristics comparable to those of Nafionl based systems, and could therefore be of utility in microscaled fuel cell implementations. (C) 2011 Elsevier B.V. All rights reserved.