The aim of this study was to investigate preparation of novel and high proton-conducting membranes and characterization of their properties and performances for proton exchange membrane fuel cells (PEMFCs) operating at low temperatures. A new class of non-fluorinated PVA/PWA/GPTES/MPTMS/P2O5/GA hybrid composite membranes was prepared in a sol-gel method. Swelling was observed at room temperature for all the composites. The behavior of the conductivity in various temperatures and humidity conditions was determined. A maximum conductivity value of 0.025 S/cm was found at a 140 degrees C and 50% relative humidity conditions. It is suggested that the conductivity strongly depends on the nature of the organic/inorganic components as well as on the acid concentration. X-ray diffraction (XRD) results demonstrated that this membrane had an amorphous phase, and Fourier-transform infrared spectroscopy (FTIR) results confirmed the formation of the composite. Finally, membrane electrode assemblies with a loading of 0.1 mg/cm(2) of Pt/C on a prepared electrode produced a current density of 309 mA/cm(2) at a voltage of 0.5V. (c) 2012 Elsevier B.V. All rights reserved.