화학공학소재연구정보센터
Journal of Chemical Physics, Vol.112, No.12, 5364-5369, 2000
Predicting the gas-liquid critical point from the second virial coefficient
We show that whereas the critical point is very sensitive to the range of interaction, the second virial coefficient has a fairly constant value at the critical temperature. This enables us to predict the critical temperature with fair accuracy. We discuss the connection between the second virial coefficient as a predictor for the critical temperature and the second virial coefficient as predictor in crystal growth as was proposed by George and Wilson [A. George and W. W. Wilson, Acta Crystallogr., Sec. D: Biol. Crystallogr. 50, 361 (1994)]. (C) 2000 American Institute of Physics. [S0021-9606(00)51212-4].