화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.22, No.8, 859-863, August, 2014
DOI10.1007/s13233-014-2113-y  Export Citation
Design, Synthesis and Characterization of End Group Functionalized Regioregular P3HT Prepared by an Externally Initiated Polymerization Using Organozincs
Seung-Hoi Kim†
  • Department of Chemistry, Dankook University, Chungnam, 330-174, Korea
E-mail:
A facile synthetic protocol for preparing highly regioregular, end group functionalized poly(3-hexylthiophene)s has been developed. The desired polymers have been successfully prepared via externally initiated polycondensation using an organozinc/Ni-catalyst complex prepared by a simple reaction of organozinc and Ni(dppe)Cl2. The resulting polymers were characterized using 1H NMR, UV-Vis spectrometer, GPC and MALDI-TOF MS.
Keywords:poly(3-hexylthiophene) (P3HT);end group functionalization;externally initiated polymerization;organozinc.
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