화학공학소재연구정보센터
Journal of Polymer Science Part B: Polymer Physics, Vol.52, No.6, 477-484, 2014
Processing and Properties of Melt Spun Polylactide-Multiwall Carbon Nanotube Fiber Composites
This article reports on the fabrication of oriented composite fibers between polylactide (PLA) and multiwall carbon nanotube (MWNT). The fibers were fabricated using a custom-built melt fiber-drawing setup. The influence of processing parameters on the final fiber diameter and on the orientation were characterized and optimized. Composite fibers were fabricated at various MWNT contents. Addition of low amounts of MWNT (0.25-1 wt %) to PLA did not have a significant effect on the diameters of the fibers. Observations of the composite morphology under STEM indicated preferential orientation of the MWNTs along the draw direction of the fibers. Increasing amounts of MWNTs was found to increase crystallization kinetics and content. The crystalline content had a direct and profound implication on the mechanical properties with 0.5-wt % MWNT fibers having the highest crystalline content and also the highest Young's modulus. (c) 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014, 52, 477-484