Honeycomb-like nanocomposite Ti-Ag-N films are prepared by pulsed bias arc ion plating, and for the first time served as surface modification layer on TA1 titanium as bipolar plates for unitized regenerative fuel cells (URFCs). Phase structure and surface morphology of the coated samples are investigated by XRD and SEM. Corrosion resistance of bare Ti plates and Ti-Ag-N coated samples is evaluated in simulated URFC conditions, and the interface contact resistance (ICR) between bipolar plates and carbon papers is measured before and after potentiostatic polarization tests. Ti2N phase with a preferred orientation of (1 1 0) plane is observed in the Ti-Ag-N film. SEM observation indicates that the film appears honeycomb-like and forms a nanocomposite microstructure with Ag nanoparticles embedded in Ti2N matrix. Compared to bare titanium plates, the coated sample shows improved corrosion resistance and ultra-low ICR (2 m Omega cm(2) under a compaction pressure of 1.4 MPa). The superior conductivity of the coated sample is attributed to nanocomposite microstructure containing highly conductive Ag nanoparticles, and honeycomb-like rough surface obtained in this study. Nanocomposite Ti-Ag-N coated titanium bipolar plate exhibits prominent interfacial conductivity and excellent corrosion resistance at high potential, being a promising candidate as bipolar plate for applications in URFCs. (C) 2011 Elsevier B.V. All rights reserved.