Highly flexible, binder-free, MoO3 nanobelt/graphene film electrode is prepared by a two-step microwave hydrothermal method. Graphene is first prepared by an ultra-fast microwave hydrothermal method and then mixed with MoO3 solution to synthesize the MoO3 nanobelt/graphene composite, which exhibits the combination of stacked graphene sheets and uniform MoO3 nanobelts with widths of 200-500 nm and lengths of 5-10 mu m. The charge-discharge measurements show that the as-synthesized MoO3/graphene hybrid materials demonstrate excellent rate capability, large capacity, and good cycling stability compared to the pure MoO3 film. An initial discharge capacity of 291 mAh g(-1) can be obtained at 100 mA g(-1), with a capacity of 172 mAh g(-1) retained after 100 cycles. The results show that the MoO3/graphene designed in this study can be used as a free-standing cathode material in rechargeable bendable Lithium batteries. (c) 2012 Elsevier B.V. All rights reserved.