화학공학소재연구정보센터
Journal of Chemical Technology and Biotechnology, Vol.67, No.2, 176-182, 1996
Kinetics of Acetic-Acid Addition to Epichlorohydrin in the Presence of Chromium Acetate and Chromic Anhydride
The kinetics of the reaction between acetic acid and epichlorohydrin in the presence of chromium acetate and chromic anhydride have been studied. The isolation method revealed the reagents reacted with partial orders. A reduction of chromium from the oxidation level +6 to +3 has been observed when chromic anhydride was used as catalyst. A mathematical model for the overall process has been developed and the mechanism of reaction discussed.