화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korea Polymer Journal, Vol.8, No.5, 215-223, October, 2000
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Synthesis and Characterization of Novel Aromatic Polyimides from Bis(3-aminophenyl)3,5-bis(trifluoromethyl)phenyl Phosphine Oxide
Kwang Un Jeong, Jang Joo Kim, and Tae Ho Yoon†
  • Department of Materials Science and Engineering, Kwangju Institute of Science and Technology, 1 Oryong-dong, Buk-gu, Kwangju 500-712, Korea
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A novel diamine monomer, containing fluorine and phosphine oxide, bis(3-aminophenyl)3,5-bis(trifluoromethyl)phenyl phosphine oxide (mDA6FPPO), was prepared via Grignard reaction, and utilized to prepared polymides with dianhydrides such as PMDA, 6FDA, BTDA or ODPA, by the conventional two-step route; preparation of poly(amic acid), followed by solution imidization. The polymides were characterized by FT-IR, NMR, and DSC with intrinsic viscosity and refractive index also being evaluated. A phosphine oxide containing monomer, bis(3-aminophenyl) phenyl phosphine oxide (mDAPPO)and a commercial 3,3-diaminodiphenyl sulfone (mDDS) were also used for comparison. The polyimides derived from mDA6FPPO exhibited high Tg, excellent solubility and low birefringence.
  1. Ghosh MK, Mittal KL, Polyimides: Fundamentals and Applications, Marcel Dekker, New York, 1996 (1996)
  2. Feger C, Franke H, Polyimides: Fundamentals and Applications, M.K. Ghosh and K.L. Mittal, Eds., Marcel Dekker, New York, 1996, pp 759 (1996)
  3. Sasaki S, Nish S, Polyimides: Fundamentals and Applications, M.K. Ghosh and K.L. Mittal, Eds., Marcel Dekker, New York, 1996, pp 71 (1996)
  4. Matsuura T, Hasuda Y, Nishi S, Yamada N, Macromolecules, 24, 5001 (1991) 
  5. Brink MH, Brandom DK, Wilkes GL, Mcgrath JE, Polymer, 35(23), 5018 (1994) 
  6. Lakshmanan P, Srinivas S, Wilkes GL, McGrath JE, Polym. Preprints, 36(1), 264 (1995)
  7. Hedrick JL, Charlier Y, Dipietro R, Jayaraman S, Mcgrath JE, J. Polym. Sci. A: Polym. Chem., 34(14), 2867 (1996) 
  8. Hedrick JL, Cha HJ, Miller RD, Yoon DY, Brown HR, Srinivasan S, Di Pietro R, Cook RF, Hummel JP, Klaus DP, Liniger EG, Simonyi EE, Macromolecules, 30(26), 8512 (1997) 
  9. Critchley JP, Grattan PA, Whitte MA, Pippet JS, J. Polym. Sci. A: Polym. Chem., 10, 1789 (1972) 
  10. Moy TM, DePorter CD, McGrath JE, Polymer, 34, 819 (1993) 
  11. Tesoro G, Wu Y, Adhes. Sci. Technol., 5, 771 (1991)
  12. Lee YL, Gunger A, Yoon TH, McGrath JE, J. Adhes., 55, 167 (1995)
  13. Park YR, Yoon TH, Yuck JI, Lee SG, Polym.(Korea), 22(6), 901 (1998)
  14. Wang S, Ji Q, Tchatchoua CN, Shultz AR, McGrath JE, J. Polym. Sci. B: Polym. Phys., 37(15), 1849 (1999) 
  15. Martinez-Nunez MF, Sekharipuram VN, McGrath JE, Polym. Preprints, 35, 709 (1994)
  16. Ando S, Matuura T, Sasaki S, Chemtech., Dec., 20 (1994)