This paper reports the synthesis of highly loaded SnO2/mesoporous carbon (MC) nanohybrid through a facile chemical solution process and subsequent annealing methodology, by using a novel three-dimensional (3D) MC as a buffering and conducting matrix. Owing to its unique structural characteristics, the MC-SnO2 nanohybrid anode exhibits markedly improved cycling stability and rate capability compared to pure SnO2 nanoparticles, facilitating its application in advanced Li-ion batteries (LIBs) with long cycle life and high power density. (C) 2013 Elsevier B.V. All rights reserved.