Journal of Power Sources, Vol.247, 587-593, 2014
Effect of the co-spun anode functional layer on the performance of the direct-methane microtubular solid oxide fuel cells
NiO-YSZ/porous YSZ (NiO-YSZ/p-YSZ) dual-layer hollow fibers have been fabricated by a co-spinning-sintering method, on which a dense YSZ films has been formed by a dip-coating and sintering process. A LSM-YSZ ink has been dip-coated on the dense YSZ films as cathode, while the Cu-CeO2 carbon-resistant catalyst has been impregnated in the p-YSZ layer to form double-anode supported micro tubular fuel cells (MT-SOFCs). The thickness of the Ni-YSZ layer, so called anode functional layer (AFL), is controlled from 74 mu m to 13 mu m by varying the spinning rates of the NiO-YSZ dopes. The maximum power density of an MT-SOFC, which is fabricated based on a thin co-spun AFL, reaches 566 mW cm(-2) operated at 850 degrees C fed with dry methane, and is stably operated for 85 h without power declination. (C) 2013 Elsevier B.V. All rights reserved.
Keywords:Micro tubular solid oxide fuel cell;Dual-layer hollow fiber;Anode functional layer;Carbon-resistance;Co-spinning-sintering