화학공학소재연구정보센터
Journal of Power Sources, Vol.255, 404-409, 2014
Carbon-tolerant solid oxide fuel cells using NiTiO3 as an anode internal reforming layer
In this work, adding a NiTiO3 (NTO) reforming layer is firstly adopted as a low cost method to improve the carbon tolerance in solid oxide fuel cells. XRD patterns suggest that NTO has a good chemical compatibility with the YSZ electrolyte, and NTO can be totally reduced to Ni and TiO2 when exposing to the H-2 atmosphere. Maximum power densities for the cells with the NTO layers at 700 degrees C are 270 mWcm(-2) with wet H-2 fuel, and 236 mWcm(-2) with wet methane fuel, respectively. Improved discharging stability for the cells with NTO layers has also been observed. The current density remains unchanged for the cells with NTO layers during a 26 h test, while it drops to zero within 1 h for the cells without NTO. Above electro-performance and long term stability tests suggest that fabricating a NTO reforming layer on the anode surface is an efficient and inexpensive method to realize highly carbon tolerant SOFCs. (C) 2014 Elsevier B.V. All rights reserved.