Journal of Power Sources, Vol.261, 227-237, 2014
Interfacial fracture resistance of the joint of a solid oxide fuel cell glass-ceramic sealant with metallic interconnect
Interfacial cracking resistance of a joint between a glass ceramic sealant (GC-9) and interconnect stainless steel (Crofer 22 H) for planar solid oxide fuel cells is investigated. Interfacial fracture energy is measured at room temperature to 800 degrees C using a four-point bending test technique. A heat treatment of 100 h or 1000 h at 800 degrees C is applied for studying the thermal aging effect. Results show the variation trend of interfacial fracture energy with temperature is similar for all given material conditions. Interfacial fracture energy increases with temperature to reach a peak value at 700 degrees C and then drops at temperature above 700 degrees C. A 100-h aging treatment does not change the interfacial fracture energy significantly, compared to the non-aged condition. The 1000 h-aged joint, however, has greater interfacial fracture energy than the non-aged and 100 h-aged joints at 700 degrees C-800 degrees C. Two types of cracking path in the interior of fracture surface are identified. Firstly, delamination takes place at the interface between the glass-ceramic substrate and chromate layer. Secondly, cracking occurs within the chromate layer. However, for the 1000 h-aged joints tested at 700 degrees C-800 degrees C, fracture at the highly oxidized, peripheral regions takes place within the glass-ceramic layer. (c) 2014 Elsevier B.V. All rights reserved.
Keywords:Planar solid oxide fuel cell;Glass-ceramic sealant;Metallic interconnect;Interfacial fracture energy;Thermal aging