Polyvinylidenedifluoride-hexafluoropropylene, (P(VdF-HFP))-based polymer electrolytes, as separators for lithium batteries, were prepared through different polymer/solvent (N,N-dimethylformamide, DMF) ratios and physicochemically investigated. Scanning electron microscopy measurements have shown a homogeneously distributed porosity within the membranes, with moderately tortuous pathways, resulting in a liquid uptake up to 77 wt.% with respect to the overall weight and conduction values above 10(-3) S cm(-1) at room temperature. Prolonged cycling tests, performed on Li/Sn-C and Li/LiFePO4 half-cells based on P(VdF-HFP) polymer electrolyte separator membranes, have evidenced nominal capacities ranging from 70% to 90% of the theoretical value with very good capacity retention and charge/discharge efficiency close at 100% even at high current rates. A capacity decay is observed at high current regime, associated to the diffusion phenomena occurring within the electrode and the polymer electrolyte separator membrane. (C) 2014 Elsevier B.V. All rights reserved.