Materials Chemistry and Physics, Vol.146, No.1-2, 121-128, 2014
Polarized infrared reflectance study of free standing cubic GaN grown by molecular beam epitaxy
Optical properties of free standing cubic gallium nitride grown by molecular beam epitaxy system are investigated by a polarized infrared (IR) reflectance technique. A strong reststrahlen band, which reveals the bulk-like optical phonon frequencies, is observed. Meanwhile, continuous oscillation fringes, which indicate the sample consists of two homogeneous layers with different dielectric constants, are observed in the non-reststrahlen region. By obtaining the first derivative of polarized IR reflectance spectra measured at higher angles of incidence, extra phonon resonances are identified at the edges of the reststrahlen band. The observations are verified with the theoretical results simulated based on a multi-oscillator model. (C) 2014 Elsevier B.V. All rights reserved.
Keywords:Nitrides;Fourier transform infrared spectroscopy (FTIR);Optical properties;Phonons;Dielectric properties