A polycrystalline stannates perovskites Sr1-xErxSnO3-delta (x = 0.00, 0.01 and 0.03) were synthesized by sol-gel method and their vibrational properties were investigated using Raman scattering. The substitution of Er in the Sr site, results in a slight change of the position of the Raman spectrum bands. The differential scanning calorimetry (DSC) shows two phase transitions at 532 K and 634 K for Sr0.99Er0.01SnO3-delta. The dielectric behavior of each solid solution (x = 0.01 and x = 0.03) has been studied as a function of temperature and frequency and has confirmed the observed phase transitions. The diffuseness of the phase transitions of these materials enhances with the increasing of erbium content. The dielectric constant showed a strong increase near the phase transitions temperature which value depends with frequency. This phenomenon is usually observed in relaxor materials. The conduction and the dielectric relaxation are attributed to hopping of electrons among Sn2+ and Sn4+ ions. (C) 2013 Elsevier Ltd. All rights reserved.