화학공학소재연구정보센터
Materials Science Forum, Vol.369-3, 269-276, 2001
Long term oxidation of FeCrAlODS alloys at high temperature
The oxidation resistance of a commercial oxide dispersion strengthened alloy (MA 956) was examined after long exposures at high temperature. Isothermal and cyclic oxidation treatments were carried out in laboratory air at 1200 degreesC and 1300 degreesC for a few thousand hours in order to study the oxide scale stability (criteria of protection and spalling of the alumina film). Chemical analyses of the substrate for increasing treatment duration revealed a continuous decrease of the matrix aluminium content due to the oxide growth. As soon as the aluminium content fell below a critical value, the alloy could no longer develop a continuous and protective alumina layer. Aluminium. nitrides were observed in the substrate beneath the oxidised surfaces. later associated with the iron rich oxide formation after the spallation of the alumina scale. A model to predict the service lifetime of industrial components was established, taking into account the critical parameters involved in the breakaway oxidation phenomenon.