Materials Science Forum, Vol.369-3, 719-726, 2001
Degradation of advanced MCrAlY coatings by oxidation and interdiffusion
The elemental depletion of MCrAlY coatings on IN 738 LC by interdiffusion and formation of Al2O3 scales has been studied. Exposure experiments on a NiCoCrAlYRe coating with 12% Al and CoNiCrAl(8%)Y coating at 1000 degreesC up to 10000 hours have been carried out. The total beta -phase depletion and consequently the decrease of the Al content of the coating and the damage of the base material by interdiffusion was determined. Additionally the development of Kirkendall pores was found to increase with time. Of special interest were investigations on the interdiffusion behaviour on different elements after two different preheating temperatures (similar to 600 degreesC, similar to 900 degreesC) during the coating process itself. After the normal heat treatment for IN 738 LC, the element distribution in the coating and base material was unchanged at 600 degreesC, but exhibited a 50 mum interdiffusion zone at 900 degreesC. With increasing preheating temperatures the adhesion strength is getting stronger and reach values larger than 200 MPa for a preheating temperature of 900 degreesC. Therefore the bond strength is mainly controlled by the preheating prior to application of the coating.