화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.30, No.12, 1533-1541, 1998
Excess enthalpies of (heptane plus methyl 1,1-dimethylethyl ether plus 1,2-dimethoxyethane) at the temperature 298.15 K and ambient pressure
Excess molar enthalpies measured at the temperature 298.15 K in a flow microcalorimeter are reported for the ternary mixture {x(1)CH(3)(CH2)(5)CH3 + x(2)(CH3)(3)COCH3 + (1 - x(1) -x(2))CH3O(CH2)(2)OCH3}. A smooth representation of the results is described and used to construct constant-enthalpy contours on a Roozeboom diagram. It is shown that good estimates of the ternary enthalpies can be obtained from the Flory theory using only the physical properties of the components and their binary mixtures.