In magneto-plasma-dynamic (MPD) arcjet generators, plasma is accelerated by electromagnetic body forces. The MPD arcjet generator can produce higher-velocity, higher-temperature, higher-density and larger-area plasmas than those of conventional thermal plasma torches. Two types of MPD arcjet generator were developed for applications to mullite, zirconia and titanium-nitride spray coatings. The MPD spray process could successfully form dense, uniform and hard ceramic coatings. In titanium nitride reactive spraying, plasma diagnostic measurement and flowfield analysis were also carried out A large amount of N and N+ was expected to be exhausted with a high velocity from the MPD generator. Both the electron temperature and the electron number density were kept high at a substrate position compared with those for conventional low-pressure thermal sprayings. A chemically active plasma with excited particles of N+, Ti, Ti+ and Ti2+ was considered to contribute to better titanium nitride coatings. All coating characteristics showed that the MPD arcjet generators had high potentials for ceramic spray coatings.