Transient reaction of adsorbed monolayer of acetic acid was used to compare the photocatalytic properties of TiO(2) (Degussa P-25),titanium silicalite (TS-1) and Ti-MCM-41. TS-1 and Ti-MCM-41 catalysts with Si/Ti ratio of 50 were prepared by in-situ crystallization. The catalysts were characterized using XRD and UV-DRS. During photocatalytic oxidation (PCO), CO(2) and HCHO were formed on P-25 TiO(2), whereas CO(2) and CH(4) formed on TS-1 and Ti-MCM-41. Acetic acid decomposed photocatalytically on P-25 TiO(2) to form CO(2), CH(4) and C(2)H(6). On the contrary, CO(2) and CH(4) were formed on TS-1 and Ti-MCM-41 during photocatalytic decomposition (PCD). The rates of product formation during PCD were lower than PCO. The TS-1 and Ti-MCM-41 catalysts were less active per gram of catalyst. However, the TS-1 and Ti-MCM-41 catalysts had much higher adsorption capacities for organics. Therefore, it seems that the TS-1 and Ti-MCM-41 catalysts have some advantages in applications to PCO of organic contaminants under conditions where the organic concentrations vary widely.