Electrochemical Reduction of SO2Cl2 Cell

Kee-Su Na; Woo-Seong Kim; Byeong-Goo Jeong; Ki-Hyung Chjo; Yong-Kook Choi

Journal of Industrial and Engineering Chemistry, Vol.2, No.1, 86-89, June, 1996

Kee-Su Na, Woo-Seong Kim, Byeong-Goo Jeong, Ki-Hyung Chjo, and Yong-Kook Choi

Dept. of Chemistry, Chonnam Nat'l Univ., Kwangju 500-757, Korea

The Electrochemical reduction of sulfuryl chloride has been studied extensively because of high power density primary batteries. Kinetic parameters of electrochemical reduction for the Sulfuryl chloride at glassy carbon electrode is investigated by cyclic voltammetry technique. Diffusion coefficient(D₀) of sulfuryl chloride reduction is observed to 1.36×10^-8 cm²/s in the LiAlC1₄/SO₂Cl₂ electrolyte solution. Also exchange rate constant (K⁰) is observed to 8.36×10^-6 cm/s.

[References]

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[1] Schlaikjer CR, Goebel F, Marincic N, J. Electrochem. Soc., 126, 513 (1979)

[2] Bowden W, Dey AN, J. Electrochem. Soc., 126, 2035 (1979)

[3] Kstone WK, Brodd RJ, J. Electrochem. Soc., 131, 2467 (1984)

[4] Madou MJ, Smith JJ, Szpak S, J. Electrochem. Soc., 134, 2794 (1987)

[5] Mosier-Boss PA, Szpak SJ, Smith JJ, Nowak RJ, J. Electrochem. Soc., 136, 2455 (1989)

[6] Vagtsky VS, Kazarinov VE, Volfkovich YM, Kanevsky LS, Beketayeva LA, J. Power Sources, 26, 427 (1989)

[7] Zhang SS, Liu QG, Yang LL, J. Electrochem. Soc., 140, L107 (1993)

[8] Chen Y, Evans JW, J. Electrochem. Soc., 140, 1833 (1993)

[9] Behl WK, J. Electrochem. Soc., 127, 1444 (1980)

[10] Aubay M, Lojou E, Messina R, Perichon J, J. Electrochem. Soc., 140, 879 (1993)

[11] Murphy RM, Liang CC, J. Electrochem. Soc., 130, 1231 (1983)

[12] Lojou E, Messina R, Perchon J, Descroix JP, Sarre GJ, J. Electrochem. Soc., 136, 293 (1989)

[13] Aubay M, Lojou E, Messina R, Perichon J, J. Electrochem. Soc., 140, 879 (1993)

[14] Blomgren GE, Leger VZ, Kalnoki-Kis T, Kronenberg ML, Brodd RJ, Proc. 11th Power Sources Symp., 583 (1979)

[15] Doddapaneni N, Electrochemical Soc. Fall Meeting, 583 (1981)

[16] Choi YK, Kim BS, Park SM, J. Electrochem. Soc., 149, 11 (1993)

[17] Kim WS, Choi YK, Chjo KH, Bull. Korean Chem. Soc., 15, 456 (1994)

[18] Bard AJ, Faulkner LR, "Electrochemical Methods," Chap. 6, Wiley, New York (1980)