화학공학소재연구정보센터
Materials Science Forum, Vol.514-516, 945-949, 2006
Piezoelectric and optical response of uniaxially stretched (VDF/TrFE) (75/25) copolymer films
The phase diagram of the poly(vinylidene fluoride-trifluorethylene) (P(VDF-TrFE)) copolymer system shows for VDF contents of 50...85 mol% a ferroelectric (FE)-paraelectric (PE) phase transition below melting temperature. Investigations on P(VDF-TrFE) 75/25 samples revealed a slight anisotropic behaviour, which leads to a strongly anisotropic stretching effect both on the phase transition and on the amount and nature of the FE phase in samples subjected to mechanical stretching along the main directions of the film. In this work, both the refractive index n(1,2) and the piezoelectric coefficient d(33) of mechanically stretched P(VDF-TrFE) have been measured for samples with different levels of permanent deformation. These parameters are found to reflect the anisotropy of the permanently deformed samples. The stretching effect is most pronounced (n(1,2)) or limited (d(33)) to the vicinity of the yielding point of the material. Above the yielding point, almost the piezoelectric d(33) coefficient of the non-deformed sample is observed for samples with large permanent deformation.