필러재료의 변화에 따른 NR-SBR 타입 엘라스토머 기반 고무재료의 기계적물성

Saban BÜLBÜL; Mustafa YASAR; Nuretttin AKÇAKALE

Polymer(Korea), Vol.38, No.5, 664-670, September, 2014

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필러재료의 변화에 따른 NR-SBR 타입 엘라스토머 기반 고무재료의 기계적물성

Effect of Changing of Filling Materials in NR-SBR Type Elastomer Based Rubber Materials on Mechanical Properties

Saban BÜLBÜL^†, Mustafa YASAR¹, and Nuretttin AKÇAKALE²

Institute of Science, Karabük University, Karabük, Turkey
¹Faculty of Technology, Karabük University, Karabük, Turkey
²Gerede Vocational High School, Abant izzet Baysal University, Bolu, Turkey

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The effects of different filling materials and stabilizers in polymer based materials that are used as shoe soles in the shoemaking industry on the mechanical properties (strength, failure, tensile, tearing, bending etc.) of the final products have been examined in this study. Natural rubber (NR RSS3) and styrene-butadiene rubber (SBR 1502) were used as the main matrix material. New compounds were formed by replacing the fillings in the general compound of the existing factory (SiO2, CaCO3) with 40% (1200 g) blast furnace flue dust, rice husk, reclaimed rubber (recycled) and wood ash. Comparison of the new compounds with the existing compounds revealed a decrease in hardness, density, dimension stability, bending, tearing, % elongation and failure strength and an increase in wearing.

Keywords:NR-SBR;rubbers;mechanical properties;fillings;elastomer.

[References]

Derouet D, Nakason C, Intharapat P, Tran QN, Gohier F, Nakason C, Eur. Polym. J., 45, 820 (2009)
Akcakale N, Philosopher of Doctorate Thesis, Sakarya University (2008)
Denac M, Musil V, Smit I, Compos. Part A, 36, 1282 (2005)
Khalil A, Sirajuddin NS, Nudrat RZ, J. Adv. Res., 5, 165 (2014)
Kumnuantip C, Sombatsompop N, Mater. Lett., 57, 3167 (2003)
Siriwardena S, Ismail H, Ishiaku US, The Effect of Filler Loading And Curing Agent Concentrastion On Rheoligal Properties of Polypropylene/Ethylene-Propylene-D ene-Terpolymer/With Rice Husk Ash Thermoplastic Elastomer Ternary Composites, University Sains, Malaysia (2001)
Sahin YM, Masters of Science Thesis, Bogazici University (2001)
Savasci OT, Uyanik N, Akovali G, Plastics and Plastic Technology, Cantay Publishing, Istanbul (1998)
Ichazo MN, Hermandez M, Albano C, Gonzales J, Proc. of the 8th Polym. of Adv. Tech. Int. Sym., Budapest, Hungary, p. 13 (2005)
Sumaila M, Ugheoke BI, Timon L, Oloyede T, Leonardo J. Sci., 5, 159 (2006)
Akcakale N, Demirer A, Nart E, Ozsert I, Academic Journals, 58, 758 (2010)
Mohan TP, Kuriakose J, Kanny K, J. Ind. Eng. Chem., 17(2), 264 (2011)
Jolene FS, Nunes RCR, Pita VJRR, Rheological Behavior of Mineral Fillers in Shoe Soles Composites, Universidad Federal do Rio, RJ, Brazil (2000)
Pasertsri S, Lagarde F, Rattanasom N, Sirisinha C, Daniel P, Polym. Test., 32, 852 (2013)
El-Nashar DE, Youssef EAM, El-Ghaffar MAA, Mater. Design, 31, 1350 (2010)
Mohan TP, Kuriakose J, Kanny K, J. Ind. Eng. Chem., 18(3), 979 (2012)
Zhou M, Yang S, Zhou Y, Qin N, He S, Lai D, Xie Z, Yuan J, Polym.(Korea), 38(1), 16 (2014)
Joseph K, Thomas S, Pavithran C, Polymer, 37(23), 5139 (1996)
Nielsen LE, Editor, Mechanical Properties of Polymers and Composites, Marcel Dekker, Inc., New York, Vol 2 (1974)
Sharifa J, Yunus WMZW, Dahlan KZHM, Ahmad MH, Polym. Test., 242, 211 (2005)
Basuli U, Lee GB, Jang SY, Oh J, Lee JH, Kim SC, Jeon ND, Huh YI, Nah C, Elast. Compos., 47, 297 (2012)
Lee JW, Joo HS, Kang SC, Chang YW, Elastomer, 41, 245 (2006)
Kim KJ, Kool JV, Elastomer, 39, 263 (2004)
Bucknall CB, Aggarwal SG, Allen G, Bevington JC, Editors, in Comprehensive Polymer Science, Pergamon, Oxford, England, Vol 7, p 27 (1989)
Lu Y, Liu L, Tian M, Geng H, Zhang L, Eur. Polym. J., 41, 589 (2005)
Akcakale N, Demirer A, Ozsert I, 6th International Advanced Technologies Symposium, Elazig, Turkey, p. 314 (1998)

[1] Derouet D, Nakason C, Intharapat P, Tran QN, Gohier F, Nakason C, Eur. Polym. J., 45, 820 (2009)

[2] Akcakale N, Philosopher of Doctorate Thesis, Sakarya University (2008)

[3] Denac M, Musil V, Smit I, Compos. Part A, 36, 1282 (2005)

[4] Khalil A, Sirajuddin NS, Nudrat RZ, J. Adv. Res., 5, 165 (2014)

[5] Kumnuantip C, Sombatsompop N, Mater. Lett., 57, 3167 (2003)

[6] Siriwardena S, Ismail H, Ishiaku US, The Effect of Filler Loading And Curing Agent Concentrastion On Rheoligal Properties of Polypropylene/Ethylene-Propylene-D ene-Terpolymer/With Rice Husk Ash Thermoplastic Elastomer Ternary Composites, University Sains, Malaysia (2001)

[7] Sahin YM, Masters of Science Thesis, Bogazici University (2001)

[8] Savasci OT, Uyanik N, Akovali G, Plastics and Plastic Technology, Cantay Publishing, Istanbul (1998)

[9] Ichazo MN, Hermandez M, Albano C, Gonzales J, Proc. of the 8th Polym. of Adv. Tech. Int. Sym., Budapest, Hungary, p. 13 (2005)

[10] Sumaila M, Ugheoke BI, Timon L, Oloyede T, Leonardo J. Sci., 5, 159 (2006)

[11] Akcakale N, Demirer A, Nart E, Ozsert I, Academic Journals, 58, 758 (2010)

[12] Mohan TP, Kuriakose J, Kanny K, J. Ind. Eng. Chem., 17(2), 264 (2011)

[13] Jolene FS, Nunes RCR, Pita VJRR, Rheological Behavior of Mineral Fillers in Shoe Soles Composites, Universidad Federal do Rio, RJ, Brazil (2000)

[14] Pasertsri S, Lagarde F, Rattanasom N, Sirisinha C, Daniel P, Polym. Test., 32, 852 (2013)

[15] El-Nashar DE, Youssef EAM, El-Ghaffar MAA, Mater. Design, 31, 1350 (2010)

[16] Mohan TP, Kuriakose J, Kanny K, J. Ind. Eng. Chem., 18(3), 979 (2012)

[17] Zhou M, Yang S, Zhou Y, Qin N, He S, Lai D, Xie Z, Yuan J, Polym.(Korea), 38(1), 16 (2014)

[18] Joseph K, Thomas S, Pavithran C, Polymer, 37(23), 5139 (1996)

[19] Nielsen LE, Editor, Mechanical Properties of Polymers and Composites, Marcel Dekker, Inc., New York, Vol 2 (1974)

[20] Sharifa J, Yunus WMZW, Dahlan KZHM, Ahmad MH, Polym. Test., 242, 211 (2005)

[21] Basuli U, Lee GB, Jang SY, Oh J, Lee JH, Kim SC, Jeon ND, Huh YI, Nah C, Elast. Compos., 47, 297 (2012)

[22] Lee JW, Joo HS, Kang SC, Chang YW, Elastomer, 41, 245 (2006)

[23] Kim KJ, Kool JV, Elastomer, 39, 263 (2004)

[24] Bucknall CB, Aggarwal SG, Allen G, Bevington JC, Editors, in Comprehensive Polymer Science, Pergamon, Oxford, England, Vol 7, p 27 (1989)

[25] Lu Y, Liu L, Tian M, Geng H, Zhang L, Eur. Polym. J., 41, 589 (2005)

[26] Akcakale N, Demirer A, Ozsert I, 6th International Advanced Technologies Symposium, Elazig, Turkey, p. 314 (1998)