Preparation and Characterizations of Two-Component Polyurethane Flame Retardant Coatings Using Bromo Modified Polyesters

Seung Jin Kim; Hong Soo Park; Ki Chang Lee; Seung Kil Kim; Eun Kyung Park

Journal of Industrial and Engineering Chemistry, Vol.3, No.1, 63-69, March, 1997

Seung Jin Kim, Hong Soo Park , Ki Chang Lee, Seung Kil Kim¹, and Eun Kyung Park²

Dept. of Chem. Eng., Myong Ji University, Yongin 449-728, Korea
¹Sam-Hwa Paints Ind. Co. Ltd., Ansan 425-110, Korea
²D. C. Regional Small and Medium Business Office, Daejon 300-092, Korea

Two-component polyurethane flame retardant coatings were prepared by blending bromo modified polyesters (BAOs) and polyisocyanate. BAOs were synthesized by polycondensation of bromoacetic acid, a flame retardant aliphatic carboxylic acid, with adipic acid, trimethylolpropane, and 1,4-butanediol. The content of bromoacetic acid was varied from 10, 20, to 3owt%. Various physical properties of these new flame retardant coatings were comparable with non-flame retardant coatings. They showed drying time of less than 4 h and sufficient pot-life time of 15-26 h, so they were proved to be flame retardant coatings with short drying time and long pot-life time. Coatings with 3owt% bromoacetic acid did not burn using the vertical burning test.

[References]

Adomshick GJ, Quinn RG, U.S. Patent, 3,509,008 (1970)
Ashton RJ, U.S. Patent, 3,560,253 (1971)
Klett MW, Das B, Euro. Patent, 287,829 (1988)
Taylor JH, Br. Patent, 935,926 (1963)
Backus JK, Bernard DL, Darr WC, Saunders JH, J. Appl. Polym. Sci., 12, 1053 (1968)
Ishizawa M, Oshima H, Electro. Eng., 103, 35 (1983)
Bhandari S, Chandra S, Paint India, 42, 397 (1992)
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Hitachi Cable KK., Japan Patent, 151,776 (1981)
Park HS, Park EK, Kim SK, Chung KT, Polym.(Korea), 19(1), 19 (1995)
Park HS, J. Korean Ind. Eng. Chem., 3(4), 670 (1992)
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Potter TA, Schmelzer HG, Baker RD, Prog. Org. Coatings, 12, 321 (1984)
Mark HF, Bikales NM, Overberger CG, Menges G, Kroschwitz JI, Encyclopedia of Polymer Science and Engineering, 2nd ed., 1, p. 656, Wiley, New York (1985)
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Lyons JW, The Chemistry and Uses of Fire Retardants, 241-280, Wiley, New York (1970)

[Referenced By]

[Related Articles]

[1] Adomshick GJ, Quinn RG, U.S. Patent, 3,509,008 (1970)

[2] Ashton RJ, U.S. Patent, 3,560,253 (1971)

[3] Klett MW, Das B, Euro. Patent, 287,829 (1988)

[4] Taylor JH, Br. Patent, 935,926 (1963)

[5] Backus JK, Bernard DL, Darr WC, Saunders JH, J. Appl. Polym. Sci., 12, 1053 (1968)

[6] Ishizawa M, Oshima H, Electro. Eng., 103, 35 (1983)

[7] Bhandari S, Chandra S, Paint India, 42, 397 (1992)

[8] Abdul M, Bhatnagar VM, Vergnaud JM, Fire Saf. J., 8, 135 (1985)

[9] Hitachi Cable KK., Japan Patent, 151,776 (1981)

[10] Park HS, Park EK, Kim SK, Chung KT, Polym.(Korea), 19(1), 19 (1995)

[11] Park HS, J. Korean Ind. Eng. Chem., 3(4), 670 (1992)

[12] Mark HF, Bikales NM, Overberger CG, Menges G, Kroschwitz JI, Encyclopedia of Polymer Science and Engineering, 2nd ed., 13, 289-290, Wiley, New York (1989)

[13] Tehranisa M, Ryntz RA, Xiao HX, Kordomenos PI, Frisch KC, J. Coat. Technol., 59, 43 (1987)

[14] David WG, Official Digest, 33, 642 (1961)

[15] Potter TA, Schmelzer HG, Baker RD, Prog. Org. Coatings, 12, 321 (1984)

[16] Mark HF, Bikales NM, Overberger CG, Menges G, Kroschwitz JI, Encyclopedia of Polymer Science and Engineering, 2nd ed., 1, p. 656, Wiley, New York (1985)

[17] Papa AJ, Proops WR, J. Appl. Polym. Sci., 17, 2463 (1973)

[18] Fenimore CP, Martin FJ, Modern Plast., 44, 141 (1966)

[19] Lyons JW, The Chemistry and Uses of Fire Retardants, 241-280, Wiley, New York (1970)