화학공학소재연구정보센터
Polymer, Vol.55, No.2, 565-571, 2014
Master curve of viscoelastic solid: Using causality to determine the optimal shifting procedure, and to test the accuracy of measured data
Viscoelastic solids such as rubber exhibit a complex elastic modulus E(omega), which depends on the frequency omega of the applied stress or strain. The modulus E(omega) can often be determined in a wide frequency range by performing measurements in a limited frequency range for many different temperatures, and then shift the frequency segments horizontally along the frequency axis to obtain a continuous master curve. We show that one can use the spectral representation of E(omega) (or 1/E(omega)), which obeys causality, to determine the optimal shifting procedure, and to test the accuracy of the measured data and the calculated master curve. (C) 2013 Elsevier Ltd. All rights reserved.