The structure and properties of hematite particles obtained by hydrolysis of ferric chloride solution doped with various kinds of amines were examined by TEM, XRD, TG-DTA, N-2 and H2O adsorption, and zeta potential measurements. The shape of precipitates was concentration dependent; they changed from large spheres (diameter : ca. 820 nm) to cubes (edge length : ca. 400 nm) via double-spheres (long axis length : ca. 600 nm) with increasing monoamine concentrations. This effect was enhanced by increasing their pK(a) values. Much pronounced effects of di- and triamines on the particle formation were observed; cubic and double-spherical particles were obtained at a much lower concentration of di-and triamines and small spherical (diameter : ca. 100 nm) and diamond-like (long axis length : ca. 100 nm) particles were further produced at higher concentration. It was suggested that the acceleration of the rate of phase transformation from beta-FeOOH to hematite induced by amines plays an important role for producing fairly uniform hematite particles with different shape and size. The hematite particles produced with amines contained small amounts of OH- ions in the lattice but were confirmed to be nearly single crystal.