화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.31, No.10, 1786-1791, October, 2014
DOI10.1007/s11814-014-0138-8  Export Citation
Catalytic conversion of cellulose into 5-hydroxymethylfurfural over chromium trichloride in ionic liquid
Shui Wang, Yizhen Du, Wenqian Zhang, Xiaowei Cheng, and Jidong Wang†
  • Beijing Key Laboratory of Membrane Science and Technology, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China
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An efficient method for converting cellulose into 5-hydroxymethylfurfural (5-HMF) using an inexpensive ionic liquid tetrabutylammonium chloride (TBAC) and relatively low-toxicity catalyst of chromium (III) trichloride (CrCl3·6H2O) was developed. The effects of hydrochloric acid loading, catalyst dosage, reaction temperature and time on the yield of 5-HMF were surveyed to achieve optimal reaction conditions. A 5-HMF yield of 43.7% was obtained within 90 min at 140 ℃using oil-bath heating. Glucose and starch were also investigated as feedstock to produce 5- HMF in TBAC/CrCl3·6H2O system, in which the 5-HMF yield was considerable. After 5-HMF was extracted, TBAC/CrCl3·6H2O could be used for several runs.
Keywords:Cellulose;5-Hydroxymethylfurfural;CrCl3·6H2O;TBAC;Ionic Liquid
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