In this study, poly(vinylidene fluoride) (PVDF) hollow fiber membranes were fabricated via thermally induced phase separation (TIPS) method using 28% PVDF polymer and 72% triacetin solvent. The dope solutions were prepared at four different extrusion temperatures (140 degrees C, 150 degrees C, 160 degrees C and 170 degrees C). The fabricated membranes were characterized using scanning electron microscopy (SEM), mercury porosimeter to measure membrane average pore diameter, gas permeation test was employed to measure membrane effective surface porosity. The separation of carbon dioxide (CO2) from methane (CH4) by using a gas-liquid membrane contactor was studied in order to confirm the potential of the process using the fabricated hollow fiber membranes. The experiments were performed in a membrane contactor constructed with the fabricated microporous PVDF hollow fibers. Aqueous sodium hydroxide (NaOH) solution was utilized as the liquid absorbent. The effect of the gas flow rate on the CO2 flux was investigated. It was found that the PVDF membranes exhibited increased pore size, water contact angle, membrane strength, membrane porosity, effective surface porosity with preparation temperature. Countercurrent flow mode was employed: the CO2 flux increased with membrane extrusion temperatures. (C) 2012 Elsevier B.V. All rights reserved.