Knowledge of the wetting characteristic of mineral surfaces is very important in enhancing the efficiency of separation of valuable minerals from gangue using froth flotation or oil agglomeration. In this paper a capillary rise technique was used to characterize the glass beads surface modified with cationic surfactant. The glass microspheres were used as model particles with a spherical shape and smooth surface to eliminate the roughness effect. The value of the contact angle for water was found to be 21.5 for unmodified beads, and 61.8, 89.7, 68.4 for 0.1, 1.0, 10 mg/g(solid) of CTAB, and 39.8, 68.6, 87.9 for 0.1, 1.0, 10 mg/g(solid) of DDAHCl, respectively. Data revealed that the adsorption of surfactant onto glass beads decreased the value of the electron donor component, -, which defines the hydrophobicity of the surface. Also, the property of the surface was investigated by flotation and oil agglomeration experiments. It was observed that particles with low value of contact angle for water and high for 1-bromonaphthalene and low value of - were floated with a recovery equal to 91.1 and 83.1% for CTAB and DDAHCl, respectively, and effectively agglomerated. This indicates that the capillary rise method can be successfully used to predict the wetting properties of solid particles in mineral processing.