Pyrolysis Characteristics of Acrylonitrile-Butadiene-Styrene Resin

Hyun Chul Jun; Sea Cheon Oh; Hae Pyeong Lee; Hee Taik Kim; Kyong Ok Yoo

Journal of Industrial and Engineering Chemistry, Vol.5, No.2, 143-149, June, 1999

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Pyrolysis Characteristics of Acrylonitrile-Butadiene-Styrene Resin

Hyun Chul Jun, Sea Cheon Oh , Hae Pyeong Lee , Hee Taik Kim , and Kyong Ok Yoo^†

Department of Chemical Engineering, Hanyang University, Seoul 133-791, Korea

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The pyrolysis characteristics of acrylonitrile-butadiene-styrene resin were investigated at various heating rates. Methane, ethane and ethylene were major gaseous products from pyrolysis of acrylonitrile-butadiene-styrene resin. The recovered oil products were mainly composed of styrene monomer and benzene, and showed the calorific value of 8400∼9000 cal/g, which may be suitable as fuel oil. In order to obtain the kinetic parameters of ABS pyrolysis, the dynamic thermogravimetric analysis curve and its derivative have been analyzed using a variety of analytical methods reported in the literature.

Keywords:pyrolysis;ABS resin;kinetic analysis

[References]

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[Referenced By]

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[1] Cypres R, Bettens B, Pyrolysis and Gasfication, p. 209, Elsevier Applied Science, London (1989)

[2] Williams PT, Besler S, J. Inst. Energy, 65, 192 (1992)

[3] McGhee B, Norton F, Snape CE, Fuel, 74, 28 (1995)

[4] Nguyen TT, J. Appl. Polym. Sci., 38, 765 (1989)

[5] Eng FP, Ishida H, J. Appl. Polym. Sci., 32, 5021 (1986)

[6] Okieimen FE, Ebhoaye JE, J. Appl. Polym. Sci., 48, 1853 (1993)

[7] WilliamsPT, Taylor DT, Fuel, 69, 1474 (1993)

[8] Cooney JD, Day M, Wiles DM, J. Appl. Polym. Sci., 28, 2887 (1983)

[9] Petrovic ZS, Zavargo ZZ, J. Appl. Polym. Sci., 32, 4353 (1986)

[10] Nam JD, Seferis JC, J. Polym. Sci. B: Polym. Phys., 29, 601 (1991)

[11] Nam JD, Seferis JC, J. Polym. Sci. B: Polym. Phys., 30, 455 (1992)

[12] Salin JM, Seferis JC, J. Appl. Polym. Sci., 47, 847 (1993)

[13] Jimenez A, Berenguer V, Lopez J, Sanchez A, J. Appl. Polym. Sci., 50, 1565 (1993)

[14] Freeman ES, Carroll B, J. Phys. Chem., 62, 394 (1958)

[15] Coats AW, Redfern JP, Nature, 201, 68 (1964)

[16] Friedman HL, J. Polym. Sci. C: Polym. Lett., 6, 183 (1964)

[17] Ozawa T, Bull. Chem. Soc. Jpn., 38, 1881 (1965)

[18] Doyle CD, J. Appl. Polym. Sci., 5, 285 (1961)