Developed countries are aspiring to increase the production of biofuels in order to reduce dependence on crude oil and also improve energy security, developing countries such as Ghana can adopt biofuel technologies to provide supports for rural developments. Bioethanol has been identified as one of the biofuels that can be developed in order to meet the targets as stipulated in Ghana's Strategic National Energy Plan (SNEP) up to 2020. The focus of this study was to identify the available feedstocks and their quantities for bioethanol production that can support this policy. The potential energy crops identified were cassava, yam and maize. However, cassava was identified to be the most suitable feedstock for bioethanol production since an average of less than 50% of its domestic supply is consumed as food. Even if best farming practices were adapted, bioethanol from yam and maize would not be significant compared to that of cassava. (C) 2012 Elsevier Ltd. All rights reserved.