Synthesizing nano-sized LiFePO4/C powders with less agglomeration using a solid state reaction method has become a hot research topic. This study synthesized nano-sized LiFePO4/C powder using FeC2O4, LiH2PO4 as raw materials and tween40 as surfactant and examined the effect of tween40 surfactant addition on LiFePO4 formation in a solid sate reaction. XRD, FTIR, SEM and TEM are used in this investigation. The results confirm the existence of interactions between the surfactant molecules and the precursor, which contribute to a uniform size distribution of the particles and a homogeneous carbon coating layer (about 8 nm) on the surface. The combination of nano-size and carbon coating plays a key role in the improvement of LiFePO4 electrochemical performance. As a result, the prepared nano-LiFePO4/C composite synthesized with tween40 showed high electrochemical performance with a discharge capacity of 155.5 and 120 mAh g(-1), respectively at room temperature of 25 degrees C and a low temperature of -20 degrees C, under the discharge rate of 0.1 C. In addition, the sample showed an excellent low temperature cycling performance with capacity retention of 99.6% (0.1 C) and 99.4% (0.5 C) respectively after 100 cycles at -20 degrees C. (C) 2013 Elsevier B.V. All rights reserved.